Ring-Opening Graft Polymerization of Propylene Carbonate onto Xylan in an Ionic Liquid
نویسندگان
چکیده
منابع مشابه
Ring-opening graft polymerization of propylene carbonate onto xylan in an ionic liquid.
The amidine organocatalyst 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) is an effective nucleophilic catalyst. Biocomposites with tuneable properties were successfully synthesized by ring-opening graft polymerization (ROGP) of propylene carbonate (PC) onto xylan using DBU as a catalyst in the ionic liquid (IL) 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The effects of reaction temperature, rea...
متن کاملOrganic Catalysis for the Ring-Opening Graft Polymerization of p-Dioxanone with Xylan in Ionic Liquid
Recently, organic catalysis has become a powerful alternative to the use of more traditional metal-based catalysts. In this study, 4-dimethylaminopyridine (DMAP), 1,8-diazabicyclo[5.4.0]undec7-ene (DBU), and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) were applied to mediate the ring-opening graft polymerization (ROGP) of p-dioxanone (PDO) with xylan-based hemicelluloses in ionic liquid 1-butyl-3...
متن کاملSynthesis and Characterization of Cellulose-graft- poly(p-dioxanone) Copolymers via Homogeneous Ring- Opening Graft Polymerization in Ionic Liquids
Cellulose-graft-poly(p-dioxanone) copolymers (cellulose-g-PPDO) were homogeneously prepared via ring-opening graft polymerization (ROP) between p-dioxanone (PDO) and hydroxyl groups of cellulose using the catalyst 4-dimethylaminoptridine (DMAP) in the ionic liquid 1-butyl-3methylimidazolium chloride (BmimCl). Chemical structures and physical properties of the cellulose-g-PPDO copolymers were ch...
متن کاملOrganocatalytic ring-opening polymerization.
Modern synthetic methods have revolutionized polymer chemistry through the development of new and powerful strategies for the controlled synthesis of complex polymer architectures.1-5 Many of these developments were spawned by new classes of transition metal catalysts for the synthesis of new polyolefin microstructures,5 the design of highly efficient families of “living” polymerization strateg...
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ژورنال
عنوان ژورنال: Molecules
سال: 2015
ISSN: 1420-3049
DOI: 10.3390/molecules20046033